以金屬無機鹽SnCl2.2H2O、CuCl2.2H2O和無水乙醇為原料,用溶膠凝膠法制備了SnO2和CuO摻雜的CuO-SnO2薄膜,并用X射線衍射、掃描電鏡、透射電鏡和電化學工作站對樣品進行了表征。結果表明:隨著退火溫度的增加,薄膜結晶性變好,晶粒長大,電學特性增強,最佳退火溫度確定為450℃。摻雜CuO的SnO2薄膜導電性好于同等條件下未摻雜的SnO2薄膜。SnO2呈四方相金紅石結構,衍射峰顯示薄膜中存在部分SnO。聚乙二醇的添加增強了SnO2的衍射峰,當超過一定添加量后將抑制晶粒的生長,并使得CuO-SnO2薄膜的導電性呈先減小后增大的趨勢。丙三醇的添加可極大改善薄膜的表面形貌,增強了SnO2的衍射峰,且導電性明顯變好。

　　關鍵詞： 二氧化錫;溶膠凝膠法;氧化銅;摻雜;電學特性

　　Abstract: The CuO-doped SnO2 composite films were grown in sol-gel method on Si(100) substrates.The impacts of the growth conditions,including the concentrations of Sn and CuO in the solution,annealing temperature,and polyethylene glycol(PEG) addition,on the microstructures and properties of the films were evaluated.The CuO doped composite films and the control sample were characterized with X-ray diffraction,scanning electron microscopy,transmission electron microscopy and electrochemical probe.The results show that the CuO-doping and annealing temperature strongly affect the microstructures and properties of the films.For instance,an increase of the annealing temperature resulted in bigger SnO2 grains,improvement of compactness,and reduction of the sheet resistance.The optimized annealing temperature was found to be 450℃.Addition of a certain amount of PEG and glycerine significantly bettered the crystallization and surface morphology of the films.

　　Keywords: SnO2 film,Sol-gel method,CuO,Doping,Electrical property

　　基金項目: 中央高校基本科研業務費專項資金(N090403001);; 教育部留學回國人員科研啟動基金(20091341-4)

　　采用溶膠凝膠法制備了四方相金紅石多晶結構SnO2 薄膜, XRD 特征衍射峰分別對應(110) , (101) ,(211) 晶面, 樣品不存在晶粒的擇優取向。300退火的SnO2 薄膜為非晶狀態, 隨退火溫度升高, 結晶性逐漸變好, 晶粒尺寸呈先增大后減小趨勢, 電阻呈略減小后再增大的趨勢。CuO 的摻雜未導致新物相產生, 卻抑制了SnO2 晶粒生長并增強了薄膜的電學特性, 薄膜晶粒呈不規則形狀, 粒徑約10 nm。EDS能譜分析發現膜中Sn 并未完全以SnO2 結構形式存在, 還有SnO 相形成。PEG的添加增強了SnO2 的(220) , (002) 晶面的生長, 但當PEG添加量超過05g 使開始明顯抑制晶粒生長。CuO-SnO2 薄膜樣品的導電性隨PEG 的添加量呈先減小后增大的趨勢, 接觸角呈先減小后增大趨勢; 丙三醇的加入改善了薄膜表面形貌, 增強了SnO2 的衍射峰, 薄膜裂紋的數量和寬度明顯減少, 導電性明顯變好, 但對接觸角影響很小。

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